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101.
Bartomiej Piasecki Anna Biernasiuk Adrianna Skiba Krystyna Skalicka-Wo
niak Agnieszka Ludwiczuk 《Molecules (Basel, Switzerland)》2021,26(24)
Many of the essential oils obtained from medicinal plants possess proven antimicrobial activity and are suitable for medicinal purposes and applications in the food industry. The aim of the present work was the chemical analysis of 19 essential oils (EOs) from seven different Cymbopogon species (C. nardus, C. citratus, C winterianus, C. flexuosus, C. schoenanthus, C. martinii, C. giganteus). Five different chemotypes were established by GC/MS and TLC assay. The EOs, as well as some reference compounds, i.e., citronellol, geraniol and citral (neral + geranial), were also tested for their antimicrobial and antibiofilm activity against methicillin-resistant Staphylococcus aureus (MRSA) by the microdilution method and direct bioautography. The toxicity of EOs was evaluated by Danio rerio ‘Zebrafish’ model assay. All examined EOs showed moderate to high activity against MRSA, with the highest activity noted for C. flexuosus—lemongrass essential oil, both in microdilution and direct autobiography method. Significant difference in the toxicity of the examined EOs was also detected. 相似文献
102.
103.
104.
Edyta Piskorska Krystyna Lawniczak-Jablonska Iraida N. Demchenko Ewa Benko Markku Heinonen 《Mikrochimica acta》2004,145(1-4):159-163
X-ray photoelectron spectroscopy (XPS) is used to estimate phase and element contents of the composites based on cubic boron nitride. A composite is a mixture of several compounds and the use of traditional X-ray diffraction for phase analysis in many cases can be difficult. By using XPS, we were able to evaluate the atomic concentration of elements and the content of different compounds of each element. SEM and XPS showed that samples are heterogeneous. The TiB2 phase, expecting from thermodynamic calculations, was formed in both investigated samples of cBN/Ti3SiC2/TiC but in different amount. The Ti3SiC2 additive was found more chemically active then TiC. 相似文献
105.
Katarzyna Dopierała Monika Rojewska Marta Skrzypiec Michał Dutkiewicz Hieronim Maciejewski Krystyna Prochaska 《Liquid crystals》2018,45(3):351-361
Polyhedral oligomeric silesquioxanes (POSS) with eight polyether substituents were mixed with the liquid crystal (LC) 4-octyloxy-4′-cyanobiphenyl and spread at the air/water interface. The surface pressure-area and surface potential-area isotherms were recorded for different weight ratios of both components. The obtained results showed that POSS molecules had beneficial influence on LC monolayer improving its stability and rigidity. Moreover, it was found that some LC–POSS mixtures collapse reversibly and form multilayer films on the top of LC monolayer. On the other hand, interfacial dilatational and shear rheology indicated decrease of elasticity of the films after mixing. Brewster angle microscopy revealed multilayer structure of the condensed film and formation of net-like structures in the expanded film. These films were successfully transferred on solid substrates using the Langmuir–Blodgett technique. The scanning electron microscopy images confirmed the film deposition and formation of networks by POSS–LC mixtures. These findings may be useful in the fabrication of electronic devices based on LCs. 相似文献
106.
Summary Two complexes formed from CuII acetate and thiazolidine-4-carboxylic acid (4-TCA) and 2-amino-4-thiazoleethanoic acid (ATAA) have been prepared and characterized by magnetic and spectroscopic techniques. The influence of the nature of ligands and solvents upon CuII e.p.r. properties was investigated for these compounds, Spin-Hamiltonian parameters from these data enabled suggestions concerning the structure of these complexes and the binding ability of the ligands. 相似文献
107.
Adam Bieniek Jan Epsztajn Krystyna K. Kulikiewicz 《Monatshefte für Chemie / Chemical Monthly》2004,38(Z1):69-77
A convenient two-step protocol preparation of ortho-alkylated (substituent with the carbomethoxy group at the end of five carbon atoms alkyl chain) aromatic carboxylic acids from benzoic acids anilides is described. Ortho-lithiation of benzanilides and subsequent reaction of the generated bis(N- and C-ortho-)-lithiated anilides with aromatic aldehydes provided 3-arylphthalides. In the next step, these phthalides were converted into 5-(2-carboxyphenyl)-5-phenylpent-2-enoic acids by treatment with 1-methoxy-1-trimethylsilyloxybuta-1,3-diene. 相似文献
108.
Fritz G. Will Krystyna Cedzynska Denton C. Linton 《Journal of Electroanalytical Chemistry》1993,360(1-2)
Reproducible tritium generation well above background has been observed in tightly closed D2SO4-containing cells in four out of four Pd wire cathodes of one type. Tritium analysis was performed before and after each experiment on the Pd, the electrolyte and the gas in the head space. No tritium generation was observed in four identical Pd cathodes in H2SO4 cells operated at the same time under the same conditions. A cyclic loading-unloading regime with low current densities, rather than the usual continuous constant current regime, was employed to attain D/Pd and H/Pd loadings of 1±0.05 reproducibly. D/Pd loadings greater than 0.8±0.05 appear to be necessary to generate tritium. The largest amount of tritium, generated in 7 days of continuous electrolysis, was 2.1 × 1011 tritium atoms, compared with a background of 4 × 109 tritium atoms. The concentration of tritium and its axial distribution in the Pd were determined and concentrations of up to 9 × 1010 atoms/g Pd were found compared with a maximum background of 5 × 108 atoms g−1. The T/D ratio in the Pd is about 100 times larger than in the electrolyte or gas and indicates that tritium generation occurs in the Pd interior rather than at its surface. No tritium generation was observed in two other types of Pd electrodes in D2SO4, despite the attainment of D/Pd ratios near 1:1. Thus high D/Pd ratios appear to be a necessary but not sufficient condition for tritium generation in D2SO4 electrolysis. 相似文献
109.
The possibility of selective preconcentration of platinum group metal ions by Donnan dialysis was investigated. The effect of sample matrix (glycine) on self diffusion of the following platinum group metal ions Pt(IV), Pd(II), Rh(III), Ir(III) and Ir(IV) was determined. To separate a sample from the receiver electrolyte (0.5M NH4Cl), anion or cation-exchange membrane were used. Excellent selective preconcentration of Pd(II) in the sample and Ir(III) in the receiver solution was achieved. Experiments performed enable to draw some conclusion on the charge sign of glycinepalladium complexes. 相似文献
110.
Krystyna Srogi 《Mikrochimica acta》2006,154(3-4):191-212
This article reviews the analysis of drugs and drug metabolites in hair by chromatographic procedures, including the pretreatment
steps, and the extraction methods. The general tendency in the last years, to highly sophisticated techniques (GC–MS–NCI,
HPLC–MS, GC–MS–MS) illustrates the constant fight for sensitivity. 相似文献